Electrical and Statistical Characterization of Reactively Sputtered TiOx Capacitors with Nickel Electrodes

Abstract

Thin film capacitors were sputtered on Si wafers with Ni electrodes in order to determine the dielectric properties of reactively sputtered TiOx with a base metal electrode system. The use of Ni electrodes gave electrically responsive devices with low frequency resistances of 350 to 9100 Ω, permittivities from 250 to 1500, and losses between 0.300 and 0.750. The large loss values have been attributed to the semiconductive nature of sub-stoichiometric TiOx. The decreased resistance is subsequently responsible for the elevated permittivities. Dielectric data was able to analyzed by a full factorial design of experiments analysis, and has be related to the activity of oxygen in the plasma during deposition. XPS characterization confirmed the proposed effects of oxygen both in and on the film during deposition.

Department(s)

Materials Science and Engineering

Document Type

Article - Journal

Document Version

Citation

File Type

text

Language(s)

English

Publication Date

2008-01-01

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