Doctoral Dissertations
Keywords and Phrases
Exploration; geochemistry; iocg; isotope; la-icp-ms; magnetite
Abstract
"Iron-oxide-copper-gold (IOCG) deposits are poorly understood mineral systems. For example, we do not know why Cu- and Co-rich IOCG deposits typically occur proximal to Fe ore deposits that are notably Cu and Co-poor, such as Iron Oxide Apatite (IOA) deposits. To better understand the formation of IOA and IOCG deposits in Missouri, USA, this PhD thesis examines the genesis of the Kratz Spring IOA and the Boss Central Dome IOCG deposits. This study presents the first constraints on formation conditions and fluid sources in the studied deposits using integrated petrographic, mineral composition, and Fe isotope analyses of oxide minerals. Observations show that the Kratz Spring deposit is primarily composed of magnetite with lesser hematite and can be sub-divided into two deposits: (i) a north deposit with magnetite formation temperatures of 650-850°C and (ii) a south deposit with magnetite formation temperatures of 350-500°C. Trace element and isotope data of oxides suggest that the two sub-deposits at Kratz Spring were formed from different fluid sources, i.e., the south deposit was formed by a juvenile magmatically exsolved fluid, while the north deposit’s had significant input of meteoric fluids. Oxide trace element chemistry and Fe isotopic analysis suggest that the magnetite ore in the Boss Central Dome deposit formed from a juvenile fluid at 300-600°C. Together, the data presented here suggest that the Kratz Spring South deposit mirrors the distant Boss Central Dome deposit more so than the adjacent Kratz Spring North deposit. This study supports linking Missouri’s IOA and IOCG deposits to a crustal-scale magmatic-hydrothermal system to explain their co-occurrence, and thereby helps to focus regional exploration efforts"-- Abstract, p. iv
Advisor(s)
Locmelis, Marek
Committee Member(s)
Awuah-Offei, Kwame, 1975-
Borrok, David M.
Hogan, John Patrick
Seeger, Cheryl M.
Wronkiewicz, David J.
Department(s)
Geosciences and Geological and Petroleum Engineering
Degree Name
Ph. D. in Geology and Geophysics
Publisher
Missouri University of Science and Technology
Publication Date
Spring 2024
Pagination
xi, 262 pages
Note about bibliography
Includes_bibliographical_references_(pages 72, 102 and 260-261)
Rights
© 2023 Brandon James Sulivan, All rights reserved
Document Type
Dissertation - Open Access
File Type
text
Language
English
Thesis Number
T 12362
Recommended Citation
Sullivan, Brandon James, "Re-evaluating Missouri’s strategic element potential: a geochemical study of the mesoproterozoic fe-cu-co-ree deposits in southeast Missouri, USA" (2024). Doctoral Dissertations. 3287.
https://scholarsmine.mst.edu/doctoral_dissertations/3287