Abstract
Conventional controlled low-strength material (CLSM) is a self-consolidating cementitious material with high flowability and low strength, traditionally composed of cement, sand, and water. This study explores the sustainable utilization of off-specification fly ash (OSFA) and bottom ash (BA), classified as industrial by-products with potential environmental hazards, to develop eco-friendly geopolymer CLSM as an alternative to conventional CLSM. Sodium hydroxide (NaOH) was used as an alkali activator to stabilize and solidify both two-part (liquid NaOH) and one-part (solid NaOH pellets) geopolymer CLSM mixtures. These mixtures were evaluated based on flowability (ASTM D6103-17) and compressive strength (< 300 psi per ACI Committee 229 guidelines for excavatability). A cost analysis was also conducted. The results demonstrated that incorporating OSFA as a cement replacement increased water demand by 15% to meet flowability requirements, while BA substitution for sand led to segregation challenges requiring mixture adjustments. For two-part mixtures, higher carbon content in OSFA necessitated an increased water-to-fly ash ratio. All self-consolidating mixtures exhibited 1-day compressive strengths ranging from 5 psi (0.03 MPa) to 87 psi (0.6 MPa). One-part mixtures showed a 1% to 34% reduction in 7-day compressive strength compared to two-part mixtures, improving excavatability. Increasing the BA-to-OSFA ratio from 1:1 to 3:1 reduced water demand due to lower surface area but increased the NaOH/OSFA ratio. This study highlights the potential of geopolymer CLSM to reduce costs by up to 94% at current NaOH prices (USD 6 per cubic yard) while repurposing hazardous industrial by-products, offering a cost-efficient, sustainable, and environmentally responsible solution for CLSM production.
Recommended Citation
A. K. VanDomelen et al., "Geopolymer CLSM with Off-Specification Fly Ash and Bottom Ash: A Sustainable Approach to Hazardous Waste Utilization," Materials, vol. 18, no. 13, article no. 3105, MDPI, Jul 2025.
The definitive version is available at https://doi.org/10.3390/ma18133105
Department(s)
Civil, Architectural and Environmental Engineering
Publication Status
Open Acess
Keywords and Phrases
bottom ash; controlled low-strength material; flowability; geopolymer; hazardous waste solidification; industrial by-product recycling; off-specification fly ash
International Standard Serial Number (ISSN)
1996-1944
Document Type
Article - Journal
Document Version
Final Version
File Type
text
Language(s)
English
Rights
© 2025 The Authors, All rights reserved.
Creative Commons Licensing

This work is licensed under a Creative Commons Attribution 4.0 License.
Publication Date
01 Jul 2025

Comments
Ameren Corporation, Grant None