Iron(III) Species Dispersed in Porous Silica Through Sol-gel Chemistry

Abstract

Fe/SiO2 catalysts have been prepared by two different sol-gel methods, cogelation and dissolution. The cogelation and dissolution preparative methods lead to xerogels with fundamentally different pore width distributions. The nature of the iron species obtained has been examined in detail by UV-visible and Mössbauer spectroscopy, and magnetic, transmission electron microscopy, and X-ray diffraction studies. There is no evidence for the presence of any ordered iron(III) oxides in the samples but all three contain two types of iron species, specifically paramagnetic high-spin iron(III) ions isolated in silica and iron(III) containing nanoparticles with a broad width distribution centered on 1.5 nm, nanoparticles that contain antiferromagnetically coupled clusters of a few ligated bridged iron(III) ions.

Department(s)

Chemistry

Keywords and Phrases

Magnetic Properties; Nanoclusters; Nanoparticles; Porous Silicon; Sol-gel Process; Transmission Electron Microscopy; X Ray Diffraction Analysis; Antiferromagnetically Coupled Clusters; Iron Species; Pore Width Distributions; Porous Silica; Silica

International Standard Serial Number (ISSN)

0022-3093

Document Type

Article - Journal

Document Version

Citation

File Type

text

Language(s)

English

Rights

© 2008 Elsevier, All rights reserved.

Publication Date

01 Jan 2008

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