Optimization of Indirect Photometric Detection of Anions in High-Performance Capillary Electrophoresis
Abstract
Optimization of the indirect photometric detection in high-performance capillary electrophoresis is demonstrated. The influences of background electrolyte (BGE) concentration, capillary diameters, linear polymers, pH of BGE and types of BGE have been studied and assessed in terms of theoretical predictions. The experimental results fit the theoretical deduction very well. At optimized conditions, sub-femtomoles of simple anions can be detected, offering a 500-fold improvement compared to previous studies, and being close to the predicted limit of detection.
Recommended Citation
Y. Ma and R. Zhang, "Optimization of Indirect Photometric Detection of Anions in High-Performance Capillary Electrophoresis," Journal of Chromatography A, vol. 625, no. 2, pp. 341 - 348, Elsevier, Nov 1992.
The definitive version is available at https://doi.org/10.1016/0021-9673(92)85218-I
Department(s)
Chemistry
Keywords and Phrases
Anion; Electrochemistry; Osmosis; Priority Journal; Spectrophotometry; Theory; Zone Electrophoresis
International Standard Serial Number (ISSN)
0021-9673
Document Type
Article - Journal
Document Version
Citation
File Type
text
Language(s)
English
Rights
© 1992 Elsevier, All rights reserved.
Publication Date
01 Nov 1992
