Homogeneous Copper(I) Catalysed Decomposition Of Dimethyl Diazomalonate. The Role Of The Counter Ion In Determining The Effective Spin Multiplicity
Abstract
The reactions of olefin-dimethyl diazomalonate-trialkyl phosphite-copper(I) halide (catalyst) systems proceed via displacement of halide from the soluble catalyst, and this step appears to be rate determining; the leaving group ability of the anion influences the effective spin multiplicity distribution of the carbenoid species.
Recommended Citation
D. S. Wulfman et al., "Homogeneous Copper(I) Catalysed Decomposition Of Dimethyl Diazomalonate. The Role Of The Counter Ion In Determining The Effective Spin Multiplicity," Journal of the Chemical Society D: Chemical Communications, no. 21, pp. 1360 - 1361, Journal of the Chemcial Society D: Chemical Communications, Jan 1971.
The definitive version is available at https://doi.org/10.1039/C29710001360
Department(s)
Chemistry
International Standard Serial Number (ISSN)
0577-6171
Document Type
Article - Journal
Document Version
Citation
File Type
text
Language(s)
English
Rights
© 2023 Journal of the Chemical Society D: Chemical Communications, All rights reserved.
Publication Date
01 Jan 1971
