The Transition Metal Chemistry of Quinuclidinone-containing Ligands-VII. Cobalt(II) and Nickel(II) Thiocyanate Complexes of 2-(n-morpholinylmethyl)-3-quinuclidinone
Complexes of cobalt(II) and nickel(II) thiocyanate with 2-(N-morpholinylmethyl)-3-quinuclidinone, MQN, were prepared by adding the metal salt to the ligand in alcoholic solutions. The resulting complexes had the stoichiometry Co(MQN)(NCS)2. C2H5OH and Ni(MQN)(NCS)2. CH3OH. A study of their magnetic and i.r. and electronic spectral properties has indicated that these complexes contain metal ions in octahedral coordination sites.
R. C. Dickinson and G. J. Long, "The Transition Metal Chemistry of Quinuclidinone-containing Ligands-VII. Cobalt(II) and Nickel(II) Thiocyanate Complexes of 2-(n-morpholinylmethyl)-3-quinuclidinone," Journal of Inorganic and Nuclear Chemistry, vol. 36, no. 6, pp. 1235-1238, Pergamon Press Ltd., Jun 1974.
The definitive version is available at https://doi.org/10.1016/0022-1902(74)80057-6
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© 1974 Pergamon Press Ltd., All rights reserved.
01 Jun 1974