The Transition Metal Chemistry of Quinuclidinone-containing Ligands-VII[1]. Cobalt(II) and Nickel(II) Thiocyanate Complexes of 2-(n-morpholinylmethyl)-3-quinuclidinone

Abstract

Complexes of cobalt(II) and nickel(II) thiocyanate with 2-(N-morpholinylmethyl)-3-quinuclidinone, MQN, were prepared by adding the metal salt to the ligand in alcoholic solutions. The resulting complexes had the stoichiometry Co(MQN)(NCS)2. C2H5OH and Ni(MQN)(NCS)2. CH3OH. A study of their magnetic and i.r. and electronic spectral properties has indicated that these complexes contain metal ions in octahedral coordination sites.

Department(s)

Chemistry

International Standard Serial Number (ISSN)

0022-1902

Document Type

Article - Journal

Document Version

Citation

File Type

text

Language(s)

English

Rights

© 1974 Pergamon Press Ltd., All rights reserved.

Publication Date

01 Jun 1974

Share

 
COinS