The Transition Metal Chemistry of Quinuclidinone-containing Ligands-VII[1]. Cobalt(II) and Nickel(II) Thiocyanate Complexes of 2-(n-morpholinylmethyl)-3-quinuclidinone

Author

Richard C. Dickinson
Gary J. Long, Missouri University of Science and TechnologyFollow

Abstract

Complexes of cobalt(II) and nickel(II) thiocyanate with 2-(N-morpholinylmethyl)-3-quinuclidinone, MQN, were prepared by adding the metal salt to the ligand in alcoholic solutions. The resulting complexes had the stoichiometry Co(MQN)(NCS)₂. C₂H₅OH and Ni(MQN)(NCS)₂. CH₃OH. A study of their magnetic and i.r. and electronic spectral properties has indicated that these complexes contain metal ions in octahedral coordination sites.

Recommended Citation

R. C. Dickinson and G. J. Long, "The Transition Metal Chemistry of Quinuclidinone-containing Ligands-VII[1]. Cobalt(II) and Nickel(II) Thiocyanate Complexes of 2-(n-morpholinylmethyl)-3-quinuclidinone," Journal of Inorganic and Nuclear Chemistry, vol. 36, no. 6, pp. 1235 - 1238, Pergamon Press Ltd., Jun 1974.

The definitive version is available at https://doi.org/10.1016/0022-1902(74)80057-6

Department(s)

Chemistry

International Standard Serial Number (ISSN)

0022-1902

Document Type

Article - Journal

Document Version

Citation

File Type

text

Language(s)

English

Rights

© 1974 Pergamon Press Ltd., All rights reserved.

Publication Date

01 Jun 1974