Title

A New Mode of Antiferromagnetic Interactions: Tris(pyrrolidyldithiocarbamato)iron(III)

Abstract

Spin delocalisation to a dithiocarbamate ligand, and consequent antiferromagnetic interaction, occurs in the d5 (t32g e2g) complex but not in the isomorphous d3 (t32g) complex; when these interactions are removed by dilution, a sextet-quartet equilibrium is apparent in the d 5 complex.

Department(s)

Chemistry

Document Type

Article - Journal

Document Version

Citation

File Type

text

Language(s)

English

Rights

© 1974 Royal Society of Chemistry, All rights reserved.


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