Department

Chemistry

Major

Physics and Chemistry

Research Advisor

Peacher, Jerry
Reddy, Prakash

Advisor's Department

Chemistry

Second Advisor's Department

Chemistry

Funding Source

UMR Opportunities for Undergraduate Research Experiences (OURE) Program

Abstract

The photo refractivity of organic-inorganic hybrid composites doped with nickel sulfide (NiS) nanocrystals is described. The nanocrystals were characterized using visible-absorption spectroscopy, energy-dispersive X-ray spectroscopy, and transmission electron microscopy. The nanocrystals were further modified by ligand exchange, lowering the over-modulation voltage without sacrificing diffraction efficiency as well as increasing the two-beam coupling gain coefficient. Photoconductivity measurements were used to determine the overall quantum efficiency of the photorefractive samples. The measurements represent a significant increase in photo refractivity when compared to other organic-inorganic hybrid photorefractive composites.

Biography

Tyler Martin Fears is a student of Physics and Chemistry at the University of Missouri at Rolla.

Research Category

Natural Sciences

Presentation Type

Poster Presentation

Document Type

Poster

Location

Havener Center, Carver-Turner Room

Presentation Date

11 April 2007, 1:00 pm - 3:00 pm

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Apr 11th, 1:00 PM Apr 11th, 3:00 PM

Photorefractivity of Organic-Inorganic Hybrid Composites Photosensitized with Nickel-Sulfide Nanocrystals

Havener Center, Carver-Turner Room

The photo refractivity of organic-inorganic hybrid composites doped with nickel sulfide (NiS) nanocrystals is described. The nanocrystals were characterized using visible-absorption spectroscopy, energy-dispersive X-ray spectroscopy, and transmission electron microscopy. The nanocrystals were further modified by ligand exchange, lowering the over-modulation voltage without sacrificing diffraction efficiency as well as increasing the two-beam coupling gain coefficient. Photoconductivity measurements were used to determine the overall quantum efficiency of the photorefractive samples. The measurements represent a significant increase in photo refractivity when compared to other organic-inorganic hybrid photorefractive composites.