Entropy and Enthalpy Change in Hydrated Ion Clusters

Author

Donald E. Hagen, Missouri University of Science and TechnologyFollow
Sung-Ho Suck Salk

Abstract

A new electrothermodynamic theory was recently developed by (Suck) Salk to treat the hydration of ions suspended in a gas containing water vapor. This theory was successfully applied to a study of the free energy of formation of both positive and negative ions and to an analysis of ion mobility data. Here the new theory is used to study entropy and enthalpy for a variety of hydrated ions. The results compare favorably to experiment and are significantly superior to Thomson theory results.

Recommended Citation

D. E. Hagen and S. S. Salk, "Entropy and Enthalpy Change in Hydrated Ion Clusters," Chemical Physics, vol. 102, no. 3, pp. 459 - 466, Elsevier, Mar 1986.

The definitive version is available at https://doi.org/10.1016/0301-0104(86)80016-7

Department(s)

Physics

International Standard Serial Number (ISSN)

0301-0104

Document Type

Article - Journal

Document Version

Citation

File Type

text

Language(s)

English

Rights

© 1986 Elsevier, All rights reserved.

Publication Date

01 Mar 1986