First-Order Phase Transition In Atom-Molecule Quantum Degenerate Mixtures With Coherent Three-Body Recombination

Abstract

We map the phase diagram of a two-mode atom-molecule Bose-Einstein condensate with Fano-Feshbach and coherent three-body recombination (cTBR) terms. The standard second-order phase transition observed as the molecular energy is tuned through the Fano-Feshbach resonance is replaced by a first-order transition when cTBR becomes prominent, due to a double-well structure in the free energy landscape. This transition is associated with atom-molecule entanglement, bistability, and molecular metastability. Our results establish cTBR as a powerful knob for quantum state engineering and control of reaction dynamics in ultracold chemistry.

Department(s)

Physics

Comments

Army Research Office, Grant W911NF-26-1-A043

International Standard Serial Number (ISSN)

1079-7114; 0031-9007

Document Type

Article - Journal

Document Version

Citation

File Type

text

Language(s)

English

Rights

© 2026 American Physical Society, All rights reserved.

Publication Date

28 Aug 2026

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