Dipole Moment And Potential Energy Functions Of The X ¹Σ + And A 1Σ+ States Of NaH

Author

W. T. Zemke
Ronald E. Olson, Missouri University of Science and TechnologyFollow
K. K. Verma
W. C. Stwalley
B. Liu

Abstract

Calculated radiative transition probabilities between all vibrational levels in the X 1Σ+ state (υ=0-21) and in the A 1Σ+ state (υ=0-32) of NaH are given. In addition, the calculated spontaneous emission lifetimes for vibrational- rotational levels (J=0,1) and the calculated dipole moments for these same levels are given. The calculations use new hybrid potential energy curves based on Rydberg-Klein-Rees (RKR) and ab initio potential curves. The RKR curve for the X state is new. The calculations use new ab initio dipole moment functions of internuclear distance. © 1984 American Institute of Physics.

Recommended Citation

W. T. Zemke et al., "Dipole Moment And Potential Energy Functions Of The X ¹Σ + And A 1Σ+ States Of NaH," The Journal of Chemical Physics, vol. 80, no. 1, pp. 356 - 364, American Institute of Physics, Jan 1984.

The definitive version is available at https://doi.org/10.1063/1.446455

Department(s)

Physics

International Standard Serial Number (ISSN)

0021-9606

Document Type

Article - Journal

Document Version

Final Version

File Type

text

Language(s)

English

Rights

© 2023 American Institute of Physics, All rights reserved.

Publication Date

01 Jan 1984