Neutron Diffraction Structural Studies of Nd₂Fe₁₇₋ₓMₓCy

Abstract

Four samples of Nd2Fe17MxCy (where M = Al, Ga, Ti, V) were synthesized using rf induction melting and C was introduced from the melt. Structural studies were then carried out using neutron diffraction. All samples were confirmed to have the Th2Zn17-type rhombohedral structure with expanded unit cell volumes. However, the volume effect, as well as the site preference of the substitutional atoms (M) is different among these samples and is different compared to their uncarbided counterparts. the C atoms were found to reside in the 9e site for all samples. The observed Curie temperature is higher for samples with higher C concentrations.

Department(s)

Physics

Second Department

Chemistry

International Standard Serial Number (ISSN)

0018-9464

Document Type

Article - Journal

Document Version

Citation

File Type

text

Language(s)

English

Rights

© 1996 Institute of Electrical and Electronics Engineers (IEEE), All rights reserved.

Publication Date

01 Jan 1996

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