Proton and Ammonia Intercalation into Layered Iron Chalcogenides

Author

Xiuquan Zhou
Brandon Wilfong
Sz Chian Liou
Halyna Hodovanets, Missouri University of Science and TechnologyFollow
Craig M. Brown
Efrain E. Rodriguez

Abstract

Structurally related to the iron-based superconductors, two new intercalated iron chalcogenides (H_0.5NH₃)Fe₂Ch₂ where Ch = S, Se have been prepared. By topochemical conversion, the protons were exchanged by lithium to form (Li_0.5NH₃)Fe₂Ch₂. Hydrogen bonding plays a significant role in the guest-host interactions of these intercalated phases.

Recommended Citation

X. Zhou et al., "Proton and Ammonia Intercalation into Layered Iron Chalcogenides," Chemical Communications, vol. 54, no. 50, pp. 6895 - 6898, Royal Society of Chemistry, Jan 2018.

The definitive version is available at https://doi.org/10.1039/c8cc02436g

Department(s)

Physics

Comments

National Science Foundation, Grant DMR-1455118

International Standard Serial Number (ISSN)

1364-548X; 1359-7345

Document Type

Article - Journal

Document Version

Citation

File Type

text

Language(s)

English

Rights

© 2018 Royal Society of Chemistry, All rights reserved.

Publication Date

01 Jan 2018

PubMed ID

29745405