Transition metal-pnictide compounds have received attention for their tendency to combine magnetism and unconventional superconductivity. Binary CoAs lies on the border of paramagnetism and the more complex behavior seen in isostructural CrAs, MnP, FeAs, and FeP. Here we report the properties of CoAs single crystals grown with two distinct techniques along with density functional theory calculations of its electronic structure and magnetic ground state. While all indications are that CoAs is paramagnetic, both experiment and theory suggest proximity to a ferromagnetic instability. Quantum oscillations are seen in torque measurements up to 31.5 T and support the calculated paramagnetic Fermiology.
D. J. Campbell et al., "CoAs: The Line of 3d Demarcation," Physical Review B, vol. 97, no. 17, article no. 174410, American Physical Society (APS), May 2018.
The definitive version is available at https://doi.org/10.1103/PhysRevB.97.174410
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10 May 2018