Abstract
Transition metal-pnictide compounds have received attention for their tendency to combine magnetism and unconventional superconductivity. Binary CoAs lies on the border of paramagnetism and the more complex behavior seen in isostructural CrAs, MnP, FeAs, and FeP. Here we report the properties of CoAs single crystals grown with two distinct techniques along with density functional theory calculations of its electronic structure and magnetic ground state. While all indications are that CoAs is paramagnetic, both experiment and theory suggest proximity to a ferromagnetic instability. Quantum oscillations are seen in torque measurements up to 31.5 T and support the calculated paramagnetic Fermiology.
Recommended Citation
D. J. Campbell et al., "CoAs: The Line of 3d Demarcation," Physical Review B, vol. 97, no. 17, article no. 174410, American Physical Society (APS), May 2018.
The definitive version is available at https://doi.org/10.1103/PhysRevB.97.174410
Department(s)
Physics
International Standard Serial Number (ISSN)
2469-9969; 2469-9950
Document Type
Article - Journal
Document Version
Final Version
File Type
text
Language(s)
English
Rights
© 2018 American Physical Society (APS), All rights reserved.
Publication Date
10 May 2018
Comments
National Science Foundation, Grant 1610349