Six samples of Ce2Fe17-xGax with nominal Ga content x equal to 0, 0.3, 0.5, 0.7, 1.0, 2.0 have been studied by powder neutron diffraction at room temperature. Both crystalline and magnetic refinements have been carried out. All six samples adopt the Th2Zn17-type rhombohedral structure. The only additional phase found is α-iron. Gallium atoms are found to have high affinity for the iron 18h site, and are absent from the 9d and 18f sites. The Ga substitution for Fe leads to an expansion of both the a and c axes. The Curie temperature increases from 238 K for Ce2Fe17 to 406 K for Ce2Fe15Ga2. Magnetic refinements on the samples with x = 0.3, 0.5, 0.7, 1.0, and 2.0 reveal that the magnetic moments of the four Fe sites are in the basal plane and that their values increase with increasing Ga content.
H. Luo et al., "Neutron Diffraction Structural Study of Ce₂Fe₁₇₋ₓGaₓ," Journal of Applied Physics, vol. 79, no. 8, American Institute of Physics (AIP), Aug 1996.
The definitive version is available at https://doi.org/10.1063/1.362048
International Standard Serial Number (ISSN)
Article - Journal
© 1996 American Institute of Physics (AIP), All rights reserved.
01 Aug 1996