A Rigourous Demonstration of the Validity of Boltzmann’s Scenario for the Spatial Homogenization of a Freely Expanding Gas and the Equilibration of the Kac Ring
Abstract
Boltzmann provided a scenario to explain why individual macroscopic systems composed of a large number N of microscopic constituents are inevitably (i.e., with overwhelming probability) observed to approach a unique macroscopic state of thermodynamic equilibrium, and why after having done so, they are then observed to remain in that state, apparently forever. We provide here rigourous new results that mathematically prove the basic features of Boltzmann’s scenario for two classical models: a simple boundary-free model for the spatial homogenization of a non-interacting gas of point particles, and the well-known Kac ring model. Our results, based on concentration inequalities that go back to Hoeffding, and which focus on the typical behavior of individual macroscopic systems, improve upon previous results by providing estimates, exponential in N, of probabilities and time scales involved.
Recommended Citation
S. De Bievre and P. E. Parris, "A Rigourous Demonstration of the Validity of Boltzmann’s Scenario for the Spatial Homogenization of a Freely Expanding Gas and the Equilibration of the Kac Ring," Journal of Statistical Physics, vol. 168, no. 4, pp. 772 - 793, Springer, Aug 2017.
The definitive version is available at https://doi.org/10.1007/s10955-017-1834-7
Department(s)
Physics
Keywords and Phrases
Approach to thermodynamic equilibrium; Expanding gas; Kac ring model
International Standard Serial Number (ISSN)
0022-4715; 1572-9613
Document Type
Article - Journal
Document Version
Citation
File Type
text
Language(s)
English
Rights
© 2018 Springer, All rights reserved.
Publication Date
01 Aug 2017
