Abstract
We measure high order harmonics from the molecule SF₆ over a large range of phase matching conditions and observe several features in the harmonics that are largely independent of such macroscopic conditions. The experimental data are then compared to the quantitative rescattering theory for the generation of harmonics from three orbitals. With this comparison, we are able to assign spectroscopic features in the harmonics to contributions from 1t1g (HOMO) and 5t1u (HOMO-1) orbitals.
Recommended Citation
B. P. Wilson and K. D. Fulfer and S. Mondal and X. Ren and J. Tross and E. D. Poliakoff and J. Jose and A. Le and R. R. Lucchese and C. A. Trallero-Herrero, "High Order Harmonic Generation from SF₆: Deconvolution of Macroscopic Effects," Journal of Chemical Physics, vol. 145, no. 22, American Institute of Physics (AIP), Dec 2016.
The definitive version is available at https://doi.org/10.1063/1.4971244
Department(s)
Physics
Keywords and Phrases
Harmonic Generation; Phase Matching; Sulfur Hexafluoride, Generation Of Harmonics; High Order Harmonic Generation; High Order Harmonics; Macroscopic Effects; Orbitals; Phase Matching Conditions; Rescattering; Spectroscopic Features, Harmonic Analysis
International Standard Serial Number (ISSN)
0021-9606
Document Type
Article - Journal
Document Version
Final Version
File Type
text
Language(s)
English
Rights
© 2016 American Institute of Physics (AIP), All rights reserved.
Publication Date
01 Dec 2016
PubMed ID
27984891
