Non-Exponential Luminescence Intensities in Exciton Trapping: Quantitative Comparison for Triplets in 1,2,4,5-tetrachlorobenzene

Author

Paul Ernest Parris, Missouri University of Science and TechnologyFollow
Vasudev M. Kenkre

Abstract

Questions regarding the dynamical information available in sensitized luminescence experiments are addressed specifically for triplet excitons in the quasi-one-dimensional system 1,2,4,5-tetrachlorobenzene (TCB). Using a recently developed generalized-master-equation theory of exciton trapping we analyze the observed time-dependent phosphorescence data from pure and mixed crystals of TCB. The consistency of the trapping data with recent spin echo measurements on TCB is discussed and the necessity of involking time-dependent energy transfer rates is carefully examined in the specific context of this system.

Recommended Citation

P. E. Parris and V. M. Kenkre, "Non-Exponential Luminescence Intensities in Exciton Trapping: Quantitative Comparison for Triplets in 1,2,4,5-tetrachlorobenzene," Chemical Physics Letters, vol. 107, no. 4-5, pp. 413 - 419, Elsevier, Jun 1984.

The definitive version is available at https://doi.org/10.1016/S0009-2614(84)80246-8

Department(s)

Physics

International Standard Serial Number (ISSN)

0009-2614

Document Type

Article - Journal

Document Version

Citation

File Type

text

Language(s)

English

Rights

© 1984 Elsevier, All rights reserved.

Publication Date

01 Jun 1984