The Effect of Coal Syngas Containing HCl on the Performance of Solid Oxide Fuel Cells: Investigations into the Effect of Operational Temperature and HCl Concentration

Abstract

The performance of solid oxide fuel cells (SOFCs) using simulated coal-derived syngas, with and without hydrogen chloride (HCl), was studied. Electrolyte-supported SOFCs were tested potentiostatically at 0.7 V at 800 and 900 °C with simulated coal syngas containing 0, 20, and 160 ppm HCl. The results from the tests without HCl show good performance with little degradation over 100 h of operation. Both 20 and 160 ppm HCl were shown to cause performance losses in the SOFCs after injection into the system. Although the tests presented in this paper show that HCl does cause degradation to SOFC performance, the cell performance was recoverable upon the removal of HCl from the fuel. Also recent results from anticipated Integrated Gasification Combined Cycle IGCC warm/hot-gas-cleanup technologies suggest that HCl will be removed to levels that will not cause any significant performance losses in SOFCs.

Department(s)

Mechanical and Aerospace Engineering

Keywords and Phrases

Coal Syngas; Experimental Performance; Hydrogen Chloride; Solid Oxide Fuel Cell

International Standard Serial Number (ISSN)

0378-7753

Document Type

Article - Journal

Document Version

Citation

File Type

text

Language(s)

English

Rights

© 2007 Elsevier B.V, All rights reserved.

Publication Date

20 Jun 2007

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