Local Structure of XAl₂O₃·(1 - X)NaPO3 Glasses. an NMR and XPS Study

Author

Richard K. Brow, Missouri University of Science and TechnologyFollow
R. James Kirkpatrick
Gary L. Turner

Abstract

Phosphate glasses are of interest because of their potential applicability in high-expansion, low-temperature glass-to-metal seals. However, their generally poor chemical durabilities limit their usefulness. Addition of Al2O3 to sodium phosphate glass has long been known to improve its aqueous durability. A series of xAl2O3·(1 - x)NaPO3 glasses were prepared and characterized by magic angle spinning nuclear magnetic resonance (MAS NMR) spectroscopy and by X-ray photoelectron spectroscopy (XPS).

Recommended Citation

R. K. Brow et al., "Local Structure of XAl₂O₃·(1 - X)NaPO3 Glasses. an NMR and XPS Study," Journal of the American Ceramic Society, American Chemical Society (ACS), Jan 1990.

The definitive version is available at https://doi.org/10.1111/j.1151-2916.1990.tb07591.x

Department(s)

Materials Science and Engineering

International Standard Serial Number (ISSN)

0002-7820; 1551-2916

Document Type

Article - Journal

Document Version

Citation

File Type

text

Language(s)

English

Rights

© 1990 American Chemical Society (ACS), All rights reserved.

Publication Date

01 Jan 1990