A Generalized Method for Determining the Crystal Nucleation and Growth Rates in Glasses by Differential Thermal Analysis
Abstract
A generalized experimental method that uses differential thermal analysis (DTA) has been developed for determining the nucleation rate (I), the crystal growth rate (U), and the concentration of quenched-in nuclei (N q) in glasses. The method is applicable even for glasses, whose I and U curves (as a function of temperature) overlap to a considerable degree. Measuring I by the conventional method may yield an overestimated value for I if the chosen crystal growth temperature is within the region of overlap between I and U. when applied to a Na2O · 2CaO · 3SiO2 glass, whose I and U curves are known to overlap considerably, the present DTA method yields values for I, U, and N q that are in excellent agreement with the same values determined by the conventional methods.
Recommended Citation
K. S. Ranisinghe et al., "A Generalized Method for Determining the Crystal Nucleation and Growth Rates in Glasses by Differential Thermal Analysis," Journal of Materials Science, Springer Verlag, Feb 2002.
The definitive version is available at https://doi.org/10.1023/A:1013769624501
Department(s)
Materials Science and Engineering
International Standard Serial Number (ISSN)
0022-2461
Document Type
Article - Journal
Document Version
Citation
File Type
text
Language(s)
English
Rights
© 2002 Springer Verlag, All rights reserved.
Publication Date
01 Feb 2002