Phosphorus Oxynitride Glasses of Variable Sodium Content

Author

Richard K. Brow, Missouri University of Science and TechnologyFollow
Mary R. Reidmeyer, Missouri University of Science and TechnologyFollow
D. E. Day, Missouri University of Science and TechnologyFollow

Editor(s)

Potter, B. G. and Zanotto, E. D. and Zwanziger, J. W.

Abstract

Nitriding phosphate glasses of variable sodium content, xNaO·(1−x)P2O5, in anhydrous ammonia gas is described. The thermal expansion coefficient and dissolution rate in water decrease with increasing P2O5 and nitrogen content The dilatometric softening point and glass transition temperature decrease with increasing P2O5 and increase with increasing nitrogen content. The water content of the as-melted glasses increases dramatically with increasing P2O5 content. The N 1s and O 1s spectra were determined with X-ray photoelectron spectroscopy.

Recommended Citation

R. K. Brow et al., "Phosphorus Oxynitride Glasses of Variable Sodium Content," Journal of Non-Crystalline Solids, Elsevier, Jan 1994.

The definitive version is available at https://doi.org/10.1016/0022-3093(94)90532-0

Department(s)

Materials Science and Engineering

International Standard Serial Number (ISSN)

0022-3093; 1873-4812

Document Type

Article - Journal

Document Version

Citation

File Type

text

Language(s)

English

Rights

© 1994 Elsevier, All rights reserved.

Publication Date

01 Jan 1994