Defect Chemistry of Mixed Ionic/electronic P-type Oxides
Editor(s)
Orlovskaya, Nina and Browning, Nigel
Abstract
The p-type perovskite structure oxides are finding use in a number of energy related applications. In particular they are being used as cathodes in fuel cells as well as dense oxygen separation membranes. The defect concentration and defect mobility determine the electrical properties. Since both of these are dependent upon the operating temperature and oxygen activity, it is important to understand how an oxide equilibrates with its environment. In this paper, a defect chemistry model for the oxidation-reduction behavior of p-type perovskites is reviewed with formulations in the (La,Sr)(Cr,Mn,Co,Fe)03 system being used as examples.
Recommended Citation
H. U. Anderson et al., "Defect Chemistry of Mixed Ionic/electronic P-type Oxides," Mixed Ionic Electronic Conducting Perovskites for Advanced Energy Systems, Springer Verlag, Jan 2004.
The definitive version is available at https://doi.org/10.1007/978-1-4020-2349-1_30
Department(s)
Materials Science and Engineering
Keywords and Phrases
Oxidation-Reduction; Electrical Conductivity; Oxygen Vacancies
Document Type
Article - Journal
Document Version
Citation
File Type
text
Language(s)
English
Rights
© 2004 Springer Verlag, All rights reserved.
Publication Date
01 Jan 2004
