The Wettability of Titanium Diboride by Molten Aluminum Drops

Abstract

Titanium diboride is widely accepted to be completely wet by liquid aluminum, yet few published wetting studies demonstrate this behavior, and reported contact angles vary widely. Sessile drop substrates from four different sources were selected and their microstructures and chemistries characterized. The results of sessile drop experiments using four techniques to modify oxide film behavior were compared. The Al-TiB2 interfaces were examined in metallographic sections or after chemical removal of the Al drop. Al wets a material containing 5.5 wt% Ni in vacuum experiments before the hold temperature of 1025∘ C is reached. The other TiB2 substrates are completely wet by Al at 1025∘ C, but only after prolonged holds under vacuum. Elimination of boron oxide from the TiB2 surface leads to a spreading condition. The role of the substrate microstructure (porosity, grain size, roughness, and carbon content) in altering the wetting kinetics is discussed.

Department(s)

Materials Science and Engineering

Keywords and Phrases

Molten Aluminum Drops; Titanium Diboride; Wettability

International Standard Serial Number (ISSN)

0022-2461

Document Type

Article - Journal

Document Version

Citation

File Type

text

Language(s)

English

Rights

© 2005 Springer Netherlands, All rights reserved.

Publication Date

01 Jan 2005

Link to Full Text

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