Abstract

Polarized x-ray absorption fine structure (XAFS) measurements at all La, Pa and Cu sites were used to study local structural features that accompany the strong Tc suppression at x similar to 1/8 in La2-xBaxCuO6. Two critical parameters regulating the strength of hole-lattice coupling in this material were determined, i.e., the direction and magnitude of CuO6 octahedra local tilts. Our findings include the existence of large disorder in the magnitude of the tilt angle about its average value {theta}, with an rms {radical}{delta} {theta}{sup 2}] {approx_equal} 2{theta}. We suggest that this large disorder strongly scatters a large fraction of states at the Fermi surface for x {approx} 1/8 leading to the observed Tc suppression.

Department(s)

Materials Science and Engineering

Keywords and Phrases

Superconductivity; Barium Doping; Mobility Gap

International Standard Serial Number (ISSN)

0909-0495

Document Type

Article - Journal

Document Version

Citation

File Type

text

Language(s)

English

Rights

© 2026 International Union of Crystallography, All rights reserved

Publication Date

1999-11-01

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