Abstract

Zirconium carbide (ZrC) was fabricated by material extrusion additive manufacturing (AM) followed by pressureless sintering at 2000°C for two hours, achieving a relative density of 90.3 %. SEM analysis revealed grains of 4.6 ± 1.8 μm; XRD confirmed single phase ZrC. A stoichiometry of ZrC0.92 was determined by XPS. Four-point flexure testing exhibited a strength of 331.3 ± 57.1 MPa and Young's modulus of 232.8 ± 13.1 GPa. Vickers hardness was 13.6 ± 1.0 GPa and 11.6 ± 0.5 GPa at 4.91 and 9.81 N, respectively. Indentation fracture resistance was 2.9 ± 0.2 MPa⋅m1/2; Griffith analysis confirmed the largest grains as the critical flaw. Thermal conductivity increased with temperature and was 13.4 W/m·K at room temperature. Electrical resistivity was 122.4 ± 0.5 μΩ⋅cm. This work adds to the viability of additively manufactured ZrC and is the first to report detailed thermal and mechanical properties for ZrC produced by material extrusion AM.

Department(s)

Materials Science and Engineering

Publication Status

Full Text Access

Comments

Missouri University of Science and Technology, Grant None

Keywords and Phrases

Additive manufacturing; Direct ink write; Material extrusion additive manufacturing; Mechanical properties; Microstructure; Thermal properties; Zirconium carbide

International Standard Serial Number (ISSN)

1873-619X; 0955-2219

Document Type

Article - Journal

Document Version

Citation

File Type

text

Language(s)

English

Rights

© 2026 Elsevier, All rights reserved.

Publication Date

01 Jul 2026

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