Abstract

Dual-phase compositionally complex ultra-high temperature ceramics were formulated by incorporating different Groups V and VI metals such as V, Nb, Ta, Cr, Mo, or W into a base composition containing the Group IV elements, Hf, Ti, and Zr. Metal distribution was predicted using first-principles-based thermodynamics simulations and compared with experimental results. Moreover, phase stability, microstructure, and mechanical properties were evaluated for all of the ceramics. Compositions containing Cr, V, Nb, or Ta formed dual-phase ceramics containing only one boride and one carbide phase, while compositions containing Mo or W developed an additional third phase. The experimental metal distribution trends generally aligned with thermodynamic predictions, except for compositions containing V, which showed unexpected segregation behavior that was influenced by complex interactions of the coexistence of boride and carbide structures. From the dual-phase ceramics, the composition containing V exhibited the highest hardness (HV1 = 25.5 ± 0.6 GPa) combined with smaller grain sizes (0.99 ± 0.33 μm for the boride and 1.15 ± 0.31 μm for the carbide phases). Our findings provide insights into phase formation and elemental segregation and help the design of next-generation dual-phase UHTCs with tailored properties.

Department(s)

Materials Science and Engineering

Publication Status

Full Text Access

Comments

Office of Naval Research, Grant N00014–21–1–2515

Keywords and Phrases

Compositionally complex ceramics; Dual-phase ultra-high temperature ceramics; Thermodynamics

International Standard Serial Number (ISSN)

1873-619X; 0955-2219

Document Type

Article - Journal

Document Version

Citation

File Type

text

Language(s)

English

Rights

© 2026 Elsevier, All rights reserved.

Publication Date

01 Feb 2026

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