Abstract

The clustering of vacancies in severely quenched Al-Li solid solution alloys, with Li content between 230 and 2760 ppm, has been studied using Doppler broadening spectroscopy. The alloy samples were initially annealed at 873 K in dry air or dry, pure nitrogen. The onset temperature for vacancy clustering in samples initially annealed in air was found to be 150 ± 10 K, 40 ± 15 K lower than for the nitrogen-annealed samples. This result is consistent with the migration of divacancies, formed as a result of the significant increase in vacancy concentration caused by Li migration to, and oxidation at, the surfaces of samples annealed in air. Li-vacancy binding may also contribute, to a lesser extent, to the ratardation of vacancy migration in the nitrogen-annealed samples. No dependence on Li content was seen in the results for the two sets of samples.

Department(s)

Materials Science and Engineering

International Standard Serial Number (ISSN)

0953-8984

Document Type

Article - Journal

Document Version

Citation

File Type

text

Language(s)

English

Rights

© 2024 IOP Publishing, All rights reserved.

Publication Date

23 Nov 1998

Included in

Metallurgy Commons

Share

 
COinS