Abstract

The size and weight of conventional imaging systems is defined by costly non-planar lenses and the complex lens assemblies required to minimize optical aberrations. The ability to engineer gradient refractive index (GRIN) optics has the potential to overcome constraints of traditional homogeneous lenses by reducing the number of components in optical systems. Here, an innovative strategy to realize this goal based on monolithic GRIN media created in Ge-As-Se-Pb chalcogenide infrared nanocomposites is presented. A gradient heat treatment to spatially modulate the volume fraction of high refractive index Pb-rich nanocrystals within a glass matrix is utilized, providing a GRIN profile while maintaining an optical transparency. A first-ever correlation of material chemistry and microstructure, processing protocol, and optical property modification resulting in a prototype GRIN structure is presented. The integrated approach and mechanistic understanding illustrated by this versatile modification paradigm provides a platform for new optical functionalities in next-generation imaging applications.

Department(s)

Materials Science and Engineering

Publication Status

Full Access

Comments

U.S. Department of Defense, Grant FA8650‐12‐C‐7225

Keywords and Phrases

chalcogenide glass-ceramics; gradient refractive index; heat treatment; optical nanocomposites; spatially selective crystallization

International Standard Serial Number (ISSN)

2195-1071

Document Type

Article - Journal

Document Version

Citation

File Type

text

Language(s)

English

Rights

© 2023 Wiley, All rights reserved.

Publication Date

01 May 2020

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