Abstract
The influence of gas sparging during copper electrolysis was studied using standard electrochemical techniques. The polarization behavior of acid copper electrolytes was determined in the presence and absence of gas sparging on vertical electrodes. Tracer ion techniques were employed to determine the effect of gas sparging and forced circulation of the electrolyte on the mass transfer characteristics of the system. In addition to the potentiodynamic scans, 3-h copper deposits were produced for morphology and orientation studies. The effect of current density and temperature on deposition were also studied. The polarization experiments have shown that a mass transfer component becomes evident at about 40% of the limiting current density at which point the deposit becomes noticeably rougher. © 1990 Chapman and Hall Ltd.
Recommended Citation
D. A. Uceda and T. J. O'Keefe, "Electrochemical Evaluation Of Copper Deposition With Gas Sparging," Journal of Applied Electrochemistry, vol. 20, no. 2, pp. 327 - 334, Springer, Mar 1990.
The definitive version is available at https://doi.org/10.1007/BF01033612
Department(s)
Materials Science and Engineering
International Standard Serial Number (ISSN)
1572-8838; 0021-891X
Document Type
Article - Journal
Document Version
Citation
File Type
text
Language(s)
English
Rights
© 2023 Springer, All rights reserved.
Publication Date
01 Mar 1990