Optimizing Additive Ratios in Alkaline Zincate Electrodeposition

Abstract

Alkaline non-cyanide zinc electrogalvanizing is utilized in some plating applications. This study was conducted to evaluate the effects of a commercial carrier, booster, and leveler in a strong zinc (37.5 g/L) and alkaline (210 g/L) plating solution. Hull cell plating was used to assess the roles of each additive on the appearance of the zinc deposits produced from synthetic solutions. Bright white deposits were generated with several different combinations of additives at current densities of 170-420 A/m2. The zinc structures were characterized using x-ray diffraction and scanning electron microscopy to understand the microstructure which produced the bright deposits in order to determine the optimal conditions leading to mirror-like deposits.

Meeting Name

9th International Symposium on Lead and Zinc Processing, PbZn 2020, held in conjunction with the 149th Annual Meeting and Exhibition, TMS 2020 (2020: Feb. 23-27, San Diego, CA)

Department(s)

Materials Science and Engineering

Research Center/Lab(s)

Center for Research in Energy and Environment (CREE)

Keywords and Phrases

Additives; Alkaline; Electrogalvanizing; Hull Cell; Non-Cyanide; Zinc; Zincate

International Standard Book Number (ISBN)

978-303037069-5

International Standard Serial Number (ISSN)

2367-1181

Document Type

Article - Conference proceedings

Document Version

Citation

File Type

text

Language(s)

English

Rights

© 2020 The Minerals, Metals & Materials Society, All rights reserved.

Publication Date

01 Feb 2020

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