The Physical Characteristics of Electrorefined Copper Starter Sheet Material

Abstract

The interaction of anode and electrolyte chemistry in copper electrorefining is complex. This is especially true with regard to the behavior of Group 15 elements (As, Sb, and Bi). To better understand this system, laboratory electrorefining experiments were conducted using commercial anodes with As/(Sb + Bi) molar ratios of 0.54 and 3.8 and an electrolyte collected from a commercial refinery. The effect of adding thiourea during plating was also examined. Twenty-one hour copper deposits were produced in the laboratory to simulate starter sheet production. The mechanical properties of the electrodeposited copper as measured by an industrially relevant empirical bend test and a one-point bend test developed by UFMG are reported. The crystal structures of the samples were also examined.

Department(s)

Materials Science and Engineering

Comments

Part of the Minerals, Metals and Materials Series book series

Keywords and Phrases

Bending; Copper; Ductility; Electrorefining; Starter sheet

International Standard Book Number (ISBN)

978-331951090-3

International Standard Serial Number (ISSN)

2367-1181

Document Type

Book - Chapter

Document Version

Citation

File Type

text

Language(s)

English

Rights

© 2017 Minerals, Metals & Materials Society (TMS), All rights reserved.

Publication Date

01 Jan 2017

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