Intragranular Nanocomposites via Internal Reduction of Carbide Solid Solutions

Abstract

A reaction-based processing technique to synthesize intragranularmetal-metal/carbide-matrix micro/nanocomposite particles via internal reduction of carbide solid solutions is introduced. The presented method is the first-demonstrated analogue of internal reduction in oxide solid solutions for non-oxide-based ceramic systems. Selected thermodynamic, kinetic, and crystallographic analyses are discussed.

Meeting Name

PRiME 2012 (2012: Oct. 7-12, Honolulu, HI)

Department(s)

Materials Science and Engineering

Comments

This work was supported by the U.S. Air Force Office of Scientific Research via Awards No. FA9550-07-1-0115 (supporting solid solution carbide syntheses, reaction experiments, and XRD and SEM analyses) and FA9550-09-1-0162 (supporting TEM/SAED analyses), and by the U.S. Department of Energy via Award No. DESC0002245 (supporting thermodynamic analyses).

Keywords and Phrases

Ceramic systems; Crystallographic analysis; Oxide solid solution; Processing technique, Solid solutions, Carbides

International Standard Serial Number (ISSN)

1938-5862; 1938-6737

Document Type

Article - Conference proceedings

Document Version

Citation

File Type

text

Language(s)

English

Rights

© 2012 Electrochemical Society., All rights reserved.

Publication Date

01 Oct 2012

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