Sodium Diffusion in Glass: III, Sodium Metaphosphate Glass

Author

Chung Lim
D. E. Day, Missouri University of Science and TechnologyFollow

Abstract

Isotope-effect measurements for ²²Na/²⁴Na diffusion were used to investigate the diffusion mechanism of Na in a sodium metaphosphate glass. A vacancy-interstitialcy multiple mechanism was in best agreement with the experimental data. Near the transition temperature Na⁺ diffusion occurs primarily by the vacancy mechanism, whereas with decreasing temperature an increasing fraction of Na^- diffuses by a noncolinear interstitialcy mechanism.

Recommended Citation

C. Lim and D. E. Day, "Sodium Diffusion in Glass: III, Sodium Metaphosphate Glass," Journal of the American Ceramic Society, vol. 61, no. 3-4, pp. 99 - 102, Wiley-Blackwell, Mar 1978.

The definitive version is available at https://doi.org/10.1111/j.1151-2916.1978.tb09247.x

Meeting Name

79th Annual Meeting, The American Ceramic Society (1977: Apr. 25, Chicago, IL): Glass Division, No. 9-G-77

Department(s)

Materials Science and Engineering

Sponsor(s)

National Science Foundation (U.S.)

Comments

Supported by the National Science Foundation under Grant No. NSF–DMR–7203248–A02.

International Standard Serial Number (ISSN)

0002-7820; 1551-2916

Document Type

Article - Conference proceedings

Document Version

Citation

File Type

text

Language(s)

English

Rights

© 1978 Wiley-Blackwell, All rights reserved.

Publication Date

01 Mar 1978