Palladium(ii) Complexes Containing 2,6-bis(Imino)Pyridines: Synthesis, Characterization, Thermal Study, and Catalytic Activity in Suzuki Reactions
Abstract
A series of palladium complexes: [(Pydim)PdCl](PdCl3) (Pydim (1): pyridine-2,6-diimine) have been synthesized from palladium dichloride and the corresponding pydim. The Pd (II) complexes have been used as catalyst in the Suzuki reaction of aryl halides. Moreover, thermal behaviors of palladium complexes have been studied in nitrogen atmosphere using TG/DTG and DTA techniques. The values of activation energy Ea, and reaction order n, the entropy change δSz.ast;, enthalpy change δH#, and Gibbs free energy change δG# of the thermal decomposition were calculated by means of several methods based on the single heating rate.
Recommended Citation
O. Dayan et al., "Palladium(ii) Complexes Containing 2,6-bis(Imino)Pyridines: Synthesis, Characterization, Thermal Study, and Catalytic Activity in Suzuki Reactions," Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry, vol. 40, no. 5, pp. 337 - 344, Taylor and Francis, May 2010.
The definitive version is available at https://doi.org/10.1080/15533174.2010.486822
Department(s)
Materials Science and Engineering
Keywords and Phrases
Activation energy; Pd(II) complexes; Pyridine-2,6-diimines; Suzuki reaction; Thermal behavior
International Standard Serial Number (ISSN)
1553-3174
Document Type
Article - Journal
Document Version
Citation
File Type
text
Language(s)
English
Rights
© 2010 Taylor and Francis, All rights reserved.
Publication Date
01 May 2010
