Nuclear Magnetic Resonance Investigation of the Structures of Phosphate and Phosphate-containing Glasses: A Review

Author

R. James Kirkpatrick
Richard K. Brow, Missouri University of Science and TechnologyFollow

Abstract

This paper presents a review of the nuclear magnetic resonance (NMR) data for phosphate and phosphate-containing glasses obtained primarily within the past 10 years and of the structural interpretations based on those data. Compositions discussed include P2O5, alkali and alkaline earth phosphates, aluminophosphates, borophosphates, fluorophosphates, and phosphate-containing silicate and aluminosilicate glasses. 31P NMR data, in conjunction with 27Al, 29Si, 11B, 7Li, and 23Na data if appropriate, have proven very powerful in providing direct evidence about the local structural environments present in the these materials and in many cases have allowed interpretation of the physical and chemical behavior of these glasses in terms of polyhedral structures. © 1995.

Recommended Citation

R. J. Kirkpatrick and R. K. Brow, "Nuclear Magnetic Resonance Investigation of the Structures of Phosphate and Phosphate-containing Glasses: A Review," Solid State Nuclear Magnetic Resonance, Elsevier, Jan 1995.

The definitive version is available at https://doi.org/10.1016/0926-2040(95)00042-O

Department(s)

Materials Science and Engineering

International Standard Serial Number (ISSN)

0926-2040

Document Type

Article - Journal

Document Version

Citation

File Type

text

Language(s)

English

Rights

© 1995 Elsevier, All rights reserved.

Publication Date

01 Jan 1995