Masters Theses

Alternative Title

The anodic oxidation of oxalic acid on gold

Abstract

"The anodic oxidation of oxalic acid on Au has been studied at 25ºC in aqueous media. The reaction rate was measured as a function of potential, oxalic acid concentration, pH, and temperature in H₂SO₄-K₂SO₄ solutions. A change in the Tafel slope in going from the lower to the higher Tafel region is explained by an alteration of the reaction mechanism due to electrical interactions between adsorbed species and the anode. Further details of an oxidation sequence involving resonant forms of oxalic acid are proposed"--Abstract, page 1.

Advisor(s)

James, William Joseph

Committee Member(s)

Johnson, James W., 1930-2002
Hanna, Samir B.

Department(s)

Chemistry

Degree Name

M.S. in Chemistry

Sponsor(s)

University of Missouri--Rolla. Graduate Center for Materials Research

Publisher

University of Missouri--Rolla

Publication Date

1970

Pagination

vii, 33 pages

Rights

© 1970 Jean Louis Lucien Desmartin, All rights reserved.

Document Type

Thesis - Open Access

File Type

text

Language

English

Subject Headings

Gold -- Anodic oxidation -- Mathematical modelsOxalic acidElectrolytic oxidation

Thesis Number

T 2492

Print OCLC #

6029379

Electronic OCLC #

869882259

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