Masters Theses

Keywords and Phrases

Structure determination

Abstract

"The effects of ammonium acetate on the solubility of anhydrous nickel (II) acetate in anhydrous acetic acid was investigated and was found to behave similar to the zinc (II), copper (II), and cobalt (II) systems. Problems with equilibrium, encountered by previous investigators, were overcome. The determination of the structure of nickel (II) acetate hemiacetate was atacked by infrared studies, preparation of adducts, cryoscopic studies, magnetic susceptibility measurements, and absorption spectra. It was found that nickel (II) acetate hemiacetate is octahedrally coordinated with two coordination sites vacant. It was shown that the binuclear cage structure common to copper (II), chromium (II), and rhodium (II) acetates is scarcely possible, in view of magnetic moment measurements. The data gathered in this work are not sufficiently interpretive to allow valid conclusions to be drawn concerning the structure of nickel (II) acetate hemiacetate"--Abstract, page ii.

Advisor(s)

Tappmeyer, Wilbur P.

Committee Member(s)

Edwards, D. R.
McDonald, H. O. (Hector O.)
Cave, Carl S., 1903-1983

Department(s)

Chemistry

Degree Name

M.S. in Chemistry

Publisher

University of Missouri at Rolla

Publication Date

1964

Pagination

viii, 86 pages

Note about bibliography

Includes bibliographical references (page 25).

Rights

© 1964 Richard J. Baird, All rights reserved.

Document Type

Thesis - Open Access

File Type

text

Language

English

Subject Headings

Nickel compounds -- Analysis
Nickel compounds -- Solubility
Nickel compounds -- Structure
Polymers -- Analysis

Thesis Number

T 1593

Print OCLC #

5958895

Electronic OCLC #

864821911

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