VLE for 1,3-butadiene with 1,2-butadiene and propyne

Author

Patrick J. Gripka

Abstract

"Vapor pressures for pure 1,3-butadiene, 1,2-butadiene and propyne and 10 binary mixtures are reported at 5, 20, 35, 50, and 65°C. An equation of state utilizing saturated vapor and liquid densities is used to correlate the experimental data. Calculated relative volatilities and saturated densities are reported for the systems 1,3-butadiene - 1,2-butadiene and 1,3-butadiene - propyne. The thermodynamic excess functions Helmholtz free energy, Gibbs free energy, entropy, enthalpy, internal energy, volume, and heat capacity are derived for the equation of state and the excess properties are reported for the two systems"--Abstract, p. iv.

Advisor(s)

David B. Manley

Committee Member(s)

Bruce E. Poling
Glen Haddock

Department(s)

Chemical and Biochemical Engineering

Degree Name

M.S. in Chemical Engineering

Publisher

University of Missouri--Rolla

Publication Date

Summer 1988

Pagination

xii, 103 pages

Note about bibliography

includes bibliographical references (pages 85-87)

Rights

© 1988 Patrick J. Gripka, All rights reserved.

Document Type

Thesis - Open Access

File Type

text

Language

English

Thesis Number

T 5720

Print OCLC #

18959275

Recommended Citation

Gripka, Patrick J., "VLE for 1,3-butadiene with 1,2-butadiene and propyne" (1988). Masters Theses. 599.
https://scholarsmine.mst.edu/masters_theses/599