Masters Theses

B. W. Jong

Abstract

"The purpose of this investigation was to study the anodic dissolution of silver in various electrolytes to determine if there existed any deviations from Faraday’s law in nitric acid-silver nitrate solutions. The effect of small additions (10-4 and 10-5 N) of Cl-, SO4=, and CrO4= on the apparent valence and dissolution potential was also studied. Current densities were varied from 0.00 to 0.07 amp·cm-2.

Based on the observed apparent valences and a grey film containing metallic particles on the anode surface, it was concluded that deviations from Faraday’s law existed under the experimental conditions. In nitric acid solutions, the deviation was due to corrosion or self-dissolution. In other solutions it seemed to be primarily due to disintegration. It was also concluded that the dissolution in these solutions was diffusion controlled "--Abstract, page ii.

Advisor(s)

James, William Joseph

Committee Member(s)

Park, Efton
Tappmeyer, Wilbur P.
Strunk, Mailand R., 1919-2008

Department(s)

Chemical and Biochemical Engineering

Degree Name

M.S. in Chemical Engineering

Publisher

University of Missouri at Rolla

Publication Date

1966

Pagination

ix, 80 pages

Note about bibliography

Includes bibliographical references (pages 77-79)

Rights

© 1966 Bing-wen Jong, All rights reserved.

Document Type

Thesis - Open Access

File Type

text

Language

English

Subject Headings

Silver -- DissolutionMetals -- Anodic oxidationSolution (Chemistry)

Thesis Number

T 1915

Print OCLC #

5977212

Electronic OCLC #

907309253

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