Masters Theses
Abstract
"The lattice constants of α. - Zr with 122 ppm H are a25 = 3.23622 ± o. 00005 Å and c25 = 5 .1526 ± 0. 0003 Å. The thermal expansion coefficients of α - Zr are found to be αa =4.6 x 10-6(0C-1) and αC =11,0 x 10-6(0C-1) in the range between 15 and 55°c.
The solid solubility limit in the Zr - H system at room temperature and independent of the H pressure was determined by the parametric x-ray method to be .310 ppm H. The a constant of Zr containing 0 to ,310 ppm H increased from 3.2360 Å (extrapolated) to 3,2378 Å and became constant (3.2364 Å) above .310 ppm H. The c constant of Zr increased within the range of 0 to .310 ppm H from 5,1508 Å (extrapolated) to 5,1572 Å and became constant (5.1572 Å) beyond .310 ppm H.
The yield and tensile strength of Zr wire increased slightly in the solid solution range and strongly in the two-phase region with increasing H content, while the elongation decreased uniformly with increasing H content.
The density of pure Zr was determined to be 6.484 g/cm3 at 25°c. With increasing H content in the solid solution region, the density of Zr HX decreased.
The perfection of the crystal structure was found to decrease with increasing H content of Zr H in the solid X solution region"-- Abstract, p. ii
Advisor(s)
Straumanis, Martin E., 1898-1973
Committee Member(s)
James, William Joseph
Frad, William A., 1909-1974
Lorey, G. Edwin
Department(s)
Materials Science and Engineering
Degree Name
M.S. in Metallurgical Engineering
Publisher
University of Missouri at Rolla
Publication Date
1964
Pagination
vii, 65 pages
Note about bibliography
Includes bibliographical references (pages 62-64)
Rights
© 1964 Dirk Heinrich Wiebe, All rights reserved.
Document Type
Thesis - Open Access
File Type
text
Language
English
Thesis Number
T 1638
Print OCLC #
5959680
Recommended Citation
Wiebe, Dirk Heinrich, "Properties and perfection of Zr-H solid solutions at room temperature." (1964). Masters Theses. 5643.
https://scholarsmine.mst.edu/masters_theses/5643