Masters Theses
Abstract
"In the thesis work, Pt-based binary, ternary, quaternary alloy anode catalysts supported on sonochemically treated multi-walled carbon nanotubes (CNTs) were synthesized with ethylene glycol reduction of corresponding metal chloride salts. Inductively coupled plasma-mass spectroscopy (ICP-MS), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and transmission electron microscopy (TEM) were used for catalyst characterization. Cyclic voltammetry for methanol oxidation and CO stripping were used to evaluate the performance of the catalysts.
PtRu nanoparticles supported on CNTs (PtRu/CNT) were prepared under a series of pHs. It was found that the PtRu particle size, composition, and catalytic activity were all sensitive to the deposition pHs. CO stripping results provided the peak potential and active surface area for each catalyst. The atomic ratios tended to approach the predetermined ratio 1:1 with the increase of pH, which is favored by bi-functional catalytic mechanism. PtRu catalysts prepared at higher pHs presented better electrochemical activity toward methanol oxidation. Humidified oxygen treatment of the PtRu/CNT led to improved activity of the catalysts toward methanol electro-oxidation, implying that Ru hydroxide is better than Ru as a co-catalyst.
PtRu, PtOs, PtRuOs, and PtRuOsIr nanoparticles supported on CNTs with atomic ratios of Pt:Ru (tr:46), Pt:Os (80:20), Pt:Ru:Os (54:36:10), and Pt:Ru:Os:Ir (44:36:10:5) were prepared. Cyclic voltammetry for the methanol oxidation and CO stripping at the catalysts showed that PtRu/CNT and PtRuOsIr/CNT have the best performance toward methanol oxidation, PtRuOs/CNT has the lowest activity, but PtOs/CNT exhibits better catalytic activity only at potential or 0.73 V"--Abstract, page iii.
Advisor(s)
Xing, Yangchuan
Committee Member(s)
Chusuei, Charles C.
Ludlow, Douglas K.
Department(s)
Chemical and Biochemical Engineering
Degree Name
M.S. in Chemical Engineering
Publisher
University of Missouri--Rolla
Publication Date
Fall 2007
Pagination
ix, 77 pages
Note about bibliography
Includes bibliographical references (pages 70-76).
Rights
© 2007 Li Ren, All rights reserved.
Document Type
Thesis - Open Access
File Type
text
Language
English
Subject Headings
Catalysts -- AnalysisFuel cells -- DesignMethanol as fuelNanotechnology
Thesis Number
T 9890
Print OCLC #
785417105
Electronic OCLC #
906029381
Recommended Citation
Ren, Li, "Synthesis and characterization of platinum-based multi-component catalysts for direct methanol fuel cells" (2007). Masters Theses. 4105.
https://scholarsmine.mst.edu/masters_theses/4105