Masters Theses
Abstract
"Several compounds containing the complex tetrachlorocuprate(II) anion, CuCl₄=, and various alkyl or aryl cations were prepared. These include bis(methylammonium)tetrachlorocuprate(II), bis(isopropylammoniumtetrachlorocuprate(II), 1,3-propanediammoniumtetrachlorocuprate(II), bis(furfuryl-ammonium)tetrachlorocuprate(II), and a series of ethylene ammonium salts. Some unsuccessful and difficult preparations are described. Spectra were taken in acetone, 4-butyrolactone, and methanoleaf An explanation of the effects of various solvents on the absorption spectrum and structure of the complex ion is given"--Abstract, page ii.
Advisor(s)
McDonald, H. O. (Hector O.)
Committee Member(s)
Tappmeyer, Wilbur P.
James, William Joseph
Department(s)
Chemistry
Degree Name
M.S. in Chemistry
Publisher
University of Missouri at Rolla
Publication Date
1967
Pagination
v, 30 pags, 6 plates
Note about bibliography
Includes bibliographical references (pages 26-27).
Rights
© 1967 Paul Douglas Griffin, All rights reserved.
Document Type
Thesis - Open Access
File Type
text
Language
English
Subject Headings
Ammonium saltsSample preparation (Chemistry)Complex ionsAbsorption spectra
Thesis Number
T 2055
Print OCLC #
5994178
Electronic OCLC #
944121348
Recommended Citation
Griffin, Paul Douglas, "Preparation and spectra of some new alkyl ammonium salts of the tetrachlorocuprate (II) ion." (1967). Masters Theses. 3192.
https://scholarsmine.mst.edu/masters_theses/3192
[(2E3A)(HCl)] (CuCl<sub>4</sub>) 200 – 340 millimicrons
Griffin_Paul_1967_1b.tif (27379 kB)
[(2E3A)(HCl)] (CuCl₄) 340 – 900 millimicrons
Griffin_Paul_1967_1c.tif (27333 kB)
[(2E3A)(HCl)] (CuCl₄) 900 – 2800 millimicrons
Griffin_Paul_1967_2a.tif (27533 kB)
(3E2A) (CuCl₄) 220 – 340 millimicrons
Griffin_Paul_1967_2b.tif (27374 kB)
(3E2A) (CuCl₄) 340 – 900 millimicrons
Griffin_Paul_1967_2c.tif (27097 kB)
(3E2A) (CuCl₄) 900 – 2800 millimicrons
