Abstract

Adsorbent components in face masks are crucial for protecting individuals exposed to dangerous situations. In this study, one porous TiO2 layer was deposited on zeolite 13X particles by coating hybrid organic/inorganic titanium alkoxide film via molecular layer deposition (MLD), followed by heat treatment to remove organic components in the MLD film. Various concentrations of Ag2O nanoparticles were impregnated on the TiO2-coated 13X particles, offering a wide range of antibacterial, antifungal, and antiviral characteristics. The obtained composite particles were characterized using X-ray photoelectron spectroscopy and thermal gravimetric analysis to study the composition and mass loading of the organic components. The surface area and pore size distribution of the samples as well as the acid sites were determined using nitrogen adsorption/desorption and temperature programmed desorption of ammonia, respectively. The composite particles were evaluated for gaseous NH3 adsorption in a continuous flow packed-bed column. The results showed a significant increase in NH3 adsorption capacity from 25.2 mg/g in 13X to 45.9 mg/g in 10-13X (13X coated with 10 MLD cycles of titanium alkoxide followed by heat treatment in air) at 20 °C, while 10-13X still exhibited 31.0 mg/g of NH3 adsorption capacity at 60 °C. In addition, carbon-doped 10-13X obtained by heat treatment of MLD coated sample under argon atmosphere increased the NH3 adsorption capacity to 54.1 mg/g. The antibacterial testing against E.coli showed that samples with lower loadings of Ag2O showed excellent antibacterial activity, demonstrating the strong antibacterial properties of the composites. Our findings showcase the potential of TiO2-coated zeolite 13X particles as a novel multi-functional filler to enhance human safety in toxic environments and provide biological protection.

Department(s)

Geosciences and Geological and Petroleum Engineering

Second Department

Materials Science and Engineering

Third Department

Biological Sciences

Fourth Department

Chemical and Biochemical Engineering

Publication Status

Open Access

Comments

Army Research Laboratory, Grant W911NF-21-2-0262

Keywords and Phrases

Ag2O Nanoparticles; Antivirus; Coating; NH3 adsorption; Porous TiO2; Zeolite 13X

International Standard Serial Number (ISSN)

1385-8947

Document Type

Article - Journal

Document Version

Citation

File Type

text

Language(s)

English

Rights

© 2024 Elsevier, All rights reserved.

Publication Date

15 Dec 2024

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