Surface Charge Effect of Nanogel on Emulsification of Oil in Water for Fossil Energy Recovery
Abstract
Crosslinked polymeric hydrogels in nano-size, termed as nanogels, have significant technological applications by stabilizing Pickering emulsion. Herein, we present our experimental observations and the results of the emulsion stability analysis on the effects of nanogel concentration, oil-to-water ratio, nanogel charge, and ambient temperature. The nanogel with neutral-charge showed extraordinarily high emulsifying ability, interfacial tension between decane and water was reduced from 51.98 mN·m-1 to less than 6.04 mN·m-1, compared to 47.5 mN·m-1 by nanosilica. When treated with neutral-charged nanogel, the oil-in-water emulsion exhibited long-term stabilization, 90% emulsion remained after one month at room temperature, showing the highest stability among the reported literature of Pickering emulsions. However, inorganic silica nanoparticles displayed emulsion stability in minutes. Of particular interest was that the emulsion volume remained 82% after thermal treatment at 65 °C for 48 h. The resulting high emulsion stability was attributed to a combination of high hydrophilicity, sufficient steric repulsion, and high surface coverage of nanogel. These observations indicated that the resulting nanogel can be a promising candidate toward enhanced oil recovery.
Recommended Citation
J. Geng et al., "Surface Charge Effect of Nanogel on Emulsification of Oil in Water for Fossil Energy Recovery," Fuel, vol. 223, pp. 140 - 148, Elsevier Ltd, Jul 2018.
The definitive version is available at https://doi.org/10.1016/j.fuel.2018.03.046
Department(s)
Geosciences and Geological and Petroleum Engineering
Keywords and Phrases
Enhanced oil recovery; Interfacial tension; Nanogel; Pickering emulsion
International Standard Serial Number (ISSN)
0016-2361
Document Type
Article - Journal
Document Version
Citation
File Type
text
Language(s)
English
Rights
© 2018 Elsevier Ltd, All rights reserved.
Publication Date
01 Jul 2018
Comments
The authors would like to express their grateful acknowledgement to the financial support from DOE under the contract of DE-FE0024558.