Abstract

Geopolymers are sustainable structural materials with properties similar to ordinary Portland cement concrete. To better understand the fundamental reaction mechanisms of geopolymers, a microwave materials characterization approach is used. In this research work, the dielectric properties (permittivity and loss factor) of common precursor powders used to make geopolymers (GPPs)—fly ash, lime, metakaolin, silica fume, slag, and zeolite—are measured over the S- and X-band frequency ranges (i.e., 2.0–4.0 GHz and 8.2–12.4 GHz, respectively). The physical characteristics, elemental composition, mineralogical properties, and phase characterization of the GPPs are then correlated to dielectric properties. Permittivity of GPP, classified as pozzolanic or latent hydraulic, is correlated with R3 calorimetry heat release. Loss factor is correlated with silica dioxide, calcium oxide, and crystalline SiO2 contents. Powders with less elemental composition diversity tend to exhibit lower permittivity values. Overall, the results reveal novel connections between the dielectric properties and chemical and physical parameters of the GPPs, which may be inputs to advanced characterization studies assessing geopolymer reactivity.

Department(s)

Electrical and Computer Engineering

Comments

National Science Foundation, Grant 1663646

Keywords and Phrases

Dielectric properties; Filled waveguide technique; Geopolymer; Microwave materials characterization; Supplementary cementitious material

International Standard Serial Number (ISSN)

1871-6873; 1359-5997

Document Type

Article - Journal

Document Version

Citation

File Type

text

Language(s)

English

Rights

© 2026 Springer, All rights reserved.

Publication Date

01 Mar 2026

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