Doctoral Dissertations
Abstract
"In this research, a study of the non-thermal method of alkaline-surfactant (AS) flooding to enhance heavy oil recovery from the Pennsylvanian Warner sandstone reservoir in Western Missouri was conducted. This work includ [sic] testing approximately 30 commercial surfactants and using a heavy oil sample with an API of 17. It was found that a number of surfactants could create stable emulsions. The viscosity of heavy oil could be reduced from 18,518 cp to 2.5 cp at 25⁰C through emulsification of certain surfactants. One of the major findings was that the emulsion created by the commercial surfactant, Igepalʼ CO-530 was stable at 25⁰C, but the oil and brine could be readily separated at 40⁰C. The addition of alkaline to Igepalʼ CO-530 produced a more stable emulsion of the heavy oil and formation brine. This emulsion separated automatically at 55⁰C. Core flooding tests were performed by the use of Igepalʼ CO-530 and alkaline NaOH at 0.6 wt% in the synthetic brine. These tests were conducted under both oil-wet and water-wet reservoir conditions, but the highest oil recovery always obtained under water-wet condition. The wettability alteration was studied through the measurement of interfacial tension and the contact angle of water on the sandstone surface treated with a model of the heavy oil sample was measured using Goniometer. Results indicated that wettability of the sandstone surface pre-treated with heavy oil could be effectively changed to water-wet by the surfactants. Additionally, spontaneous imbibition tests were conducted and it was found that the oil recovery was between 40% and 60% by nonionic surfactants, 10% and 20% by anionic surfactants, and 0% by formation water only. These results were used to conduct a simulation. The simulation results matched the experimental work, suggesting that further testing of AS flooding should be conducted"--Abstract, page iii.
Advisor(s)
Dunn-Norman, Shari
Committee Member(s)
Nygaard, Runar
Flori, Ralph E.
Neogi, P. (Partho), 1951-
Bai, Baojun
Department(s)
Geosciences and Geological and Petroleum Engineering
Degree Name
Ph. D. in Petroleum Engineering
Sponsor(s)
Schlumberger Fund
Publisher
Missouri University of Science and Technology
Publication Date
Summer 2011
Pagination
xii, 131 pages
Note about bibliography
Includes bibliographical references (pages 117-129).
Geographic Coverage
Missouri
Rights
© 2011 Rabia Mohamed Hunky, All rights reserved.
Document Type
Dissertation - Open Access
File Type
text
Language
English
Subject Headings
Chemical equilibriumEnhanced oil recovery -- MissouriHeavy oilSurface active agents
Thesis Number
T 9777
Print OCLC #
785596999
Electronic OCLC #
908695059
Recommended Citation
Hunky, Rabia Mohamed, "Enhanced heavy oil recovery by alkali-surfactant in the Pennsylvania Warner sandstone" (2011). Doctoral Dissertations. 91.
https://scholarsmine.mst.edu/doctoral_dissertations/91